Metadata you wish to add is best kept in a separate file or database for all files.
Or in another file with same name and different extension or prefix, that you can make hidden.
Relying on a file system is very tricky and your data will be bound by the restrictions and capabilities of the file system your file is stored on.
And, you cannot count on your data remaining intact as any application may wish to change these flags.
And some of those have very specific, clearly defined use, such as creation time, modification time, access time...
See, if you need only flagging the document, you may wish to use creation time, which will stay unchanged through out the live of this document (until is copied) to store your flags. :D
Very dirty business, unprofessional, unreliable and all that.
But it's a solution. Poor one, but exists.
I do not know that FAT32 or NTFS file systems support any extra bits for flagging except those already used by the OS.
Unixes EXT family FS's do support some extra bits. And even than you should be careful in case some other important application makes use of them for something.
Mac OS may support some metadata by itself, but I am not 100% sure.
On Windows, you have one more option to associate more data with a file, but I wouldn't use that as well.
Well, NTFS file system (FAT doesn't support that) has a feature called streams.
In essential, same file can have multiple data streams under itself. I.e. You have more than one file contents under same file node.
To be more clear. Same file contains two different files.
When you open the file normally only main stream is visible to the application. Applications must check whether the other streams are present and choose the one they want to follow.
So, you may choose to store metadata under the second stream of the file.
But, what if all streams are taken?
Even more, anti-virus programs may prevent you access to the metadata out of paranoya, or at least ask for a permission.
I don't know why MS included that option, probably for file duplication or something, but bad hackers made use of the fact that you can store some data, under existing regular file, that nobody is aware of.
Imagine a virus writing it's copy into another stream of one of programs already there.
All that is needed for it to start, instead of your old program next time you run it is a batch script added to task scheduler that flips two streams making the virus data the main one.
Nasty trick! So when this feature started to be abused, anti-virus software started restricting files with multiple streams, so it's like this feature doesn't exist.
If you want to add some metadata using OS's technology, use Windows registry,
but even that is unwise.
What to tell you?
Don't add metadata to files, organize a separate file, or index your data in special files with same name as the file you are refering to and in same folder.
