It isn't. fmt.Println is just making it look more precise. Println uses %g for floating point and complex numbers. The docs say...
The default precision for... %g it is the smallest number of digits necessary to identify the value uniquely.
0.3 is sufficient to identify a float32. But float64 being much more precise needs more digits.
We can use fmt.Printf and %0.20g to force both numbers to display the same precision.
f32 := float32(0.1) + float32(0.2)
f64 := float64(0.1) + float64(0.2)
fmt.Printf("%0.20g
", f32)
fmt.Printf("%0.20g
", f64)
0.30000001192092895508
0.30000000000000004441
float64 is more precise. Neither are exact as that is the nature of floating point numbers.
We can use strconv.FormatFloat to see what these numbers really are.
fmt.Println(strconv.FormatFloat(float64(f32), 'b', -1, 32))
fmt.Println(strconv.FormatFloat(f64, 'b', -1, 64))
10066330p-25
5404319552844596p-54
That is 10066330 * 2^-25 and 5404319552844596 * 2^-54.