I'm using PHP 5.3.
Using getfacl the files permissions are:
user::rwx
group::r-x
other::r-x
I also am having problems using PHP's Program execution Functions, http://www.php.net/manual/en/ref.exec.php
The program in question is wkhtmltopdf and I have it in my /usr/bin directory.
I have the convert program in my /usr/bin directory with the exact same permissions and the is_executable function returns true.